I'm no expert but this is my opinion.
From a legal/contractual perspective I believe a court would very likely say that you should comply with any reasonable and legal instruction made by your employer.
He could easily say that the collection of a debt is part of a service company A is providing to company B.
You might be able to argue that is it not reasonable because you are employed by company A for something completely different to managing debtors, and you have no skills or knowledge in that area. If say you are employed by company A in say IT support and you are now being asked to collect debts for a third party (company B), I would say that is unreasonable, but that's just my personal view.
However, if you employed as a book keeper for company A and debtor management is part of your job for company A, then it would be hard to argue that performing debtor management for company B is unreasonable.
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